| DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT | |
| Wang, Shulian1,2,3; Ma, Wanhong3; Jia, Manke3; Huang, Yingping3; Huang, YP (reprint author), China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China. | |
| 2013 | |
| Source Publication | FRESENIUS ENVIRONMENTAL BULLETIN
 |
| ISSN | 1018-4619 |
| Volume | 22Issue:2APages:549-555 |
| Abstract | Metal complex perchlorinated iron-phthalocyanine (FePcCl16) was prepared and used as a photocatalyst. The heterogeneous photocatalytic degradation of rhodamine B (RhB) and salicylic acid (SA) by FePcCl16 activated by molecular oxygen (O-2) under ultraviolet light (lambda <= 387 nm) and by hydrogen peroxide (H2O2) under visible light irradiation (lambda >= 420 nm) were studied. The experimental results indicated that organic pollutants can be effectively degraded under both ultraviolet and visible light. Under ultraviolet and visible light illumination, the removal rates of total organic carbon (TOC) for RhB reached 86.24% after 180 min and 64.73% after 300 min, respectively. The degradation process was predominated by the hydroxyl radical (center dot OH), according to the results from benzoic acid fluorescence method. The hydrophobic photocatalyst FePcCl16 was stable in aqueous solution. The photocatalytic degradation system had wide pH adaptability (3-11). The heterogeneous photocatalyst can be reused to degrade toxic organic pollutants both under ultraviolet and visible light.; Metal complex perchlorinated iron-phthalocyanine (FePcCl16) was prepared and used as a photocatalyst. The heterogeneous photocatalytic degradation of rhodamine B (RhB) and salicylic acid (SA) by FePcCl16 activated by molecular oxygen (O-2) under ultraviolet light (lambda <= 387 nm) and by hydrogen peroxide (H2O2) under visible light irradiation (lambda >= 420 nm) were studied. The experimental results indicated that organic pollutants can be effectively degraded under both ultraviolet and visible light. Under ultraviolet and visible light illumination, the removal rates of total organic carbon (TOC) for RhB reached 86.24% after 180 min and 64.73% after 300 min, respectively. The degradation process was predominated by the hydroxyl radical (center dot OH), according to the results from benzoic acid fluorescence method. The hydrophobic photocatalyst FePcCl16 was stable in aqueous solution. The photocatalytic degradation system had wide pH adaptability (3-11). The heterogeneous photocatalyst can be reused to degrade toxic organic pollutants both under ultraviolet and visible light. |
| Subtype | Article |
| Keyword | Fepccl16 Heterophotocatalysis Degradation Pollutants Mechanism |
| Department | [Wang, Shulian] Chinese Acad Sci, Inst Hydrobiol, Wuhan 430072, Peoples R China |
| WOS Headings | Science & Technology ; Life Sciences & Biomedicine |
| Funding Organization | National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Environmental Sciences & Ecology |
| WOS Subject | Environmental Sciences |
| WOS ID | WOS:000321721700012 |
| WOS Keyword | TOXIC ORGANIC POLLUTANTS ; AQUEOUS-SOLUTIONS ; IRON TETRASULFOPHTHALOCYANINE ; HYDROGEN-PEROXIDE ; NEUTRAL PHS ; IRRADIATION ; OXIDATION ; PHOTODEGRADATION ; PHTHALOCYANINE ; COMPLEX |
| Funding Organization | National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ihb.ac.cn/handle/342005/19641 |
| Collection | 藻类生物学及应用研究中心_期刊论文 |
| Corresponding Author | Huang, YP (reprint author), China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China. |
| Affiliation | 1.Chinese Acad Sci, Inst Hydrobiol, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Shulian,Ma, Wanhong,Jia, Manke,et al. DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT[J]. FRESENIUS ENVIRONMENTAL BULLETIN,2013,22(2A):549-555. |
| APA | Wang, Shulian,Ma, Wanhong,Jia, Manke,Huang, Yingping,&Huang, YP .(2013).DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT.FRESENIUS ENVIRONMENTAL BULLETIN,22(2A),549-555. |
| MLA | Wang, Shulian,et al."DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT".FRESENIUS ENVIRONMENTAL BULLETIN 22.2A(2013):549-555. |
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