IHB OpenIR  > 藻类生物学及应用研究中心  > 期刊论文
DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT
Wang, Shulian1,2,3; Ma, Wanhong3; Jia, Manke3; Huang, Yingping3; Huang, YP (reprint author), China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China.
2013
Source PublicationFRESENIUS ENVIRONMENTAL BULLETIN
ISSN1018-4619
Volume22Issue:2APages:549-555
AbstractMetal complex perchlorinated iron-phthalocyanine (FePcCl16) was prepared and used as a photocatalyst. The heterogeneous photocatalytic degradation of rhodamine B (RhB) and salicylic acid (SA) by FePcCl16 activated by molecular oxygen (O-2) under ultraviolet light (lambda <= 387 nm) and by hydrogen peroxide (H2O2) under visible light irradiation (lambda >= 420 nm) were studied. The experimental results indicated that organic pollutants can be effectively degraded under both ultraviolet and visible light. Under ultraviolet and visible light illumination, the removal rates of total organic carbon (TOC) for RhB reached 86.24% after 180 min and 64.73% after 300 min, respectively. The degradation process was predominated by the hydroxyl radical (center dot OH), according to the results from benzoic acid fluorescence method. The hydrophobic photocatalyst FePcCl16 was stable in aqueous solution. The photocatalytic degradation system had wide pH adaptability (3-11). The heterogeneous photocatalyst can be reused to degrade toxic organic pollutants both under ultraviolet and visible light.; Metal complex perchlorinated iron-phthalocyanine (FePcCl16) was prepared and used as a photocatalyst. The heterogeneous photocatalytic degradation of rhodamine B (RhB) and salicylic acid (SA) by FePcCl16 activated by molecular oxygen (O-2) under ultraviolet light (lambda <= 387 nm) and by hydrogen peroxide (H2O2) under visible light irradiation (lambda >= 420 nm) were studied. The experimental results indicated that organic pollutants can be effectively degraded under both ultraviolet and visible light. Under ultraviolet and visible light illumination, the removal rates of total organic carbon (TOC) for RhB reached 86.24% after 180 min and 64.73% after 300 min, respectively. The degradation process was predominated by the hydroxyl radical (center dot OH), according to the results from benzoic acid fluorescence method. The hydrophobic photocatalyst FePcCl16 was stable in aqueous solution. The photocatalytic degradation system had wide pH adaptability (3-11). The heterogeneous photocatalyst can be reused to degrade toxic organic pollutants both under ultraviolet and visible light.
SubtypeArticle
KeywordFepccl16 Heterophotocatalysis Degradation Pollutants Mechanism
Department[Wang, Shulian] Chinese Acad Sci, Inst Hydrobiol, Wuhan 430072, Peoples R China
WOS HeadingsScience & Technology ; Life Sciences & Biomedicine
Funding OrganizationNational Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020]
Indexed BySCI
Language英语
WOS Research AreaEnvironmental Sciences & Ecology
WOS SubjectEnvironmental Sciences
WOS IDWOS:000321721700012
WOS KeywordTOXIC ORGANIC POLLUTANTS ; AQUEOUS-SOLUTIONS ; IRON TETRASULFOPHTHALOCYANINE ; HYDROGEN-PEROXIDE ; NEUTRAL PHS ; IRRADIATION ; OXIDATION ; PHOTODEGRADATION ; PHTHALOCYANINE ; COMPLEX
Funding OrganizationNational Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020] ; National Nature Science Foundation of China [21177072, 21207079]; Outstanding Young Innovative Team Plan Project of Hubei Province [T200703]; Innovation Group Project of Hubei Province Natural Science Foundation [2009CDA020]
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Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ihb.ac.cn/handle/342005/19641
Collection藻类生物学及应用研究中心_期刊论文
Corresponding AuthorHuang, YP (reprint author), China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China.
Affiliation1.Chinese Acad Sci, Inst Hydrobiol, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.China Three Gorges Univ, Engn Res Ctr Ecoenviron Three Gorges Reservoir Re, Minist Educ, Yichang 443002, Peoples R China
Recommended Citation
GB/T 7714
Wang, Shulian,Ma, Wanhong,Jia, Manke,et al. DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT[J]. FRESENIUS ENVIRONMENTAL BULLETIN,2013,22(2A):549-555.
APA Wang, Shulian,Ma, Wanhong,Jia, Manke,Huang, Yingping,&Huang, YP .(2013).DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT.FRESENIUS ENVIRONMENTAL BULLETIN,22(2A),549-555.
MLA Wang, Shulian,et al."DEGRADATION OF POLLUTANTS BY HYDROPHOBIC FePcCl16 UNDER ULTRAVIOLET AND VISIBLE LIGHT".FRESENIUS ENVIRONMENTAL BULLETIN 22.2A(2013):549-555.
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