Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China; Inst Hydrobiol, Wuhan 430072, Peoples R China
In this work, both,solid phase microextraction (SPME) and solid phase extraction(SPE) were used to enrich organochlorine compounds in water samples and analyzed by gas chromatography with electron capture detector. The operating conditions of SPME have been studied and different kinds of solid phase were compared. Linear alkybenzene sulfonate(LAS) was added to the samples to investigate its effect on the analysis. The results indicated that polyacrylate was better than other commercial solid phases in extraction of moderated polar organic compounds and the sensitivity of SPME was higher than SPE. LAS affect much in liquid-liquid extraction and headspace SPME; but it has little effect on SPE and direct-SPME method. The applications showed that SPME was a fast and effective method in sample preparation.
Zhang, DN; Zhou, ZP; Tang, YZ; Wu, CY; Zhan, W; Xu, Y.Analysis of organchlorine compounds in water by solid phase microextraction and gas chromatography,CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,1999,27(7):768-772